Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions.
نویسندگان
چکیده
The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described.
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عنوان ژورنال:
- Chemical communications
دوره 49 81 شماره
صفحات -
تاریخ انتشار 2013